When starch fits into an amylase molecule it is broken down to maltose. This happens more often when the temperature is increased (the molecules move faster thus are more likely to collide), so the reaction speeds up. An increase of 10 degrees doubles the rate of reaction. This trend continues up to around 40 degrees Celsius (at this temperature the rate of reaction is at its optimum). Above 40 degrees the enzyme starts to break down, or denature, so the reaction rate slows down dramatically.